In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stress oriented hydrogen induced cracking sohic. The list of acronyms and abbreviations related to hisc hydrogen induced stress cracking. Hydrogen induced cracking hic phenomenon, blistering effect and. Hfi were selected for hydrogen induced cracking hic tests. Hydrogeninduced cracking hic resistance and sulphide stress corrosion ssc behavior of commercially produced api x65 and api x70 steels. Hydrogen induced cracking of subsea duplex stainless steel twi. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking ssc in cmn steels by a mechanism involving the linking of planar cracks normal to the primary. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. Hydrogen induced cracking and sulphide stress corrosion.
Corrosionpedia what is hydrogeninduced cracking hic. Hisc hydrogen induced stress cracking design and material considerations 1 day course if you would like further information on this course, please contact yeechin tang. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Cracks can develop by both transgranular and intergranular paths. Pdf hydrogen induced cracking safe materials operating limits. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. Susceptibility to sohic for linepipepressure vessel steels twi. Investigation of hydrogen embrittlement susceptibility and fracture.
Specificationsgrades asmeastm saa 516 grades 606570. Prior to 2003, hydrogen induced cracking hic testing was not incorporated into nace mr0175 iso 15156 and generally was not required for mildly sour environments i. Stressoriented hydrogeninduced cracking of l360qs steel. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Metallurgical factors in stress corrosion cracking scc and. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. Hydrogen stress cracking occurs when hydrogen penetrates highstrength or hardened metal in a state of tensile stress. Naceastm g193 1 includes the following description of hydrogen blistering. Casing pipes used in sour service are prone to two forms of failure. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry.
All different forms of corrosion are explained by nace certified. While these metals may normally be ductile in nature, the presence of hydrogen in a corroded environment can cause it to crack. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Hydrogen induced cracking hic from advanced ndt solutions. A comparative study of hydrogeninduced cracking resistances of. Because stress corrosion cracks frequently initiate at pits, and pits nucleate at sulfides, the presence of sulfides is likely to affect the scc process.
Hydrogen trapping sites and hydrogeninduced cracking in high. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Sulfide stress corrosion cracking and hydrogen induced. Hic, sour service, residual stress, erw pipe, highfrequency induction welding. Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284.
The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. Hydrogen combines with carbon within the alloy and forms methane. Similarities with hydrogen induced cracking hic, also termed hydrogen induced cracking or stepwise cracking were noted, and the solution was considered to be use of hic resistant steels. Hydrogen effect is greater near room temperature and decreases with increasing strain rate. Hydrogen induced cracking and sulfide stress cracking. Hic damage is a common degradation mechanism in the oil and gas industry. Both steels showed generalized corrosion in solution 177a, and a.
Fracture toughness properties of hic susceptible carbon steels in sour service conditions. Hydrogen induced cracking steel features, applications and. Hydrogen induced cracking and sulfide stress cracking evaluation of low alloy casing pipes. Hydrogen induced stress cracking hisc resistance and. Dec 21, 2016 hydrogen induced cracking hic and stressoriented hydrogen induced cracking sohic. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Hic is often fairly innocuous but not always, while sohic is a type of cracking that can easily lead to. By using dent specimen, hydrogen induced cracking hic cracks were found to initiate at martensiteaustenite interfaces and then propagate through retained austenite and martensite. Mar 25, 2009 nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogen induced cracking hic. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking scc, or as a result of trapped hydrogen in the steel, as in hydrogen induced cracking hic. Hydrogen induced cold cracking in a low alloy steel.
Hydrogen induced cracking of low strength steels in. There are ndt techniques focused on identifying, measuring and tracking hic, but total focusing method tfm has shown to be generally the preferred technique. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Initiation of stress corrosion cracking and hydrogeninduced. Hisc hydrogen induced stress considerations 1 day course. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process.
It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. Hydrogen permeation and hydrogeninduced cracking request pdf. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Effect of residual stresses on the hic resistance of erw pipes for. Sulfide stress cracking ssc vs hydrogen induced cracking. Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. The steps of a possible mechanism of hydrogeninduced cracking hic can be, first. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydride formation is favored by the presence of residual stress fields and is. Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. It can occur at relatively low temperatures, largely as a result of atomic hydrogen from wet h2s corrosion reactions which enter the steel and collect at inclusions or. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Pdf hydrogen induced cracking safe materials operating.
Hydrogeninduced damage is the result of electrochemical corrosion. Hydrogen evolution and permeation occur during electroplating, corrosion. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. These cracks, if undetected, can lead to failure of the pipeline. Hydrogen induced cracking hic is wet h2s cracking in steel in the form of blisters or blister cracks. Hydrogen induced cracking hic and stressoriented hydrogen induced cracking sohic. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. Hisc hydrogen induced stress cracking all acronyms. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hic test, hydrogen induced cracking test, step wise cracking.